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Regioselective deuteration and resonance Raman spectroscopic characterization of biliverdin and phycocyanobilin
Citation key ISI:A1997WW25400005
Author Knipp, B and Kneip, K and Matysik, J and Gartner, W and Hildebrandt, P and Braslavsky, S E and Schaffner, K
Pages 363-367
Year 1997
ISSN 0947-6539
Address POSTFACH 10 11 61, D-69451 WEINHEIM, GERMANY
Journal Chem. Eur. J
Volume 3
Number 3
Month MAR
Publisher WILEY-V C H VERLAG GMBH
Abstract 5-Deuteriophycocyanobilin (4), 5,15,18(2),18(2)-tetradeuteriobiliverdin IX alpha dimethyl ester (6), and 5,15-dideuteriomesobiliverdin IX alpha dimethyl ester (8) have been prepared and analyzed by resonance Raman spectroscopy in the C-H out-of-plane region, based on a previous normal-mode analysis of biliverdin XI alpha dimethyl ester (5). In this way most of the modes containing out-of-plane vibrations of the methine bridges could be assigned unambiguously. These results are of special relevance with regard to the interpretation of the resonance Raman spectra of the chromoprotein phytochrome.
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